Loading...
Explanation of efficient quenching of molecular ion vibrational motion by ultracold atoms
Stoecklin, T Halvick, P Gannouni, MA Hochlaf, M Kotochigova, S Hudson, ER
Stoecklin, T
Halvick, P
Gannouni, MA
Hochlaf, M
Kotochigova, S
Hudson, ER
Citations
Altmetric:
Genre
Journal Article
Date
2016-04-18
Advisor
Committee member
Group
Department
Permanent link to this record
Collections
Research Projects
Organizational Units
Journal Issue
DOI
10.1038/ncomms11234
Abstract
Buffer gas cooling of molecules to cold and ultracold temperatures is a promising technique for realizing a host of scientific and technological opportunities. Unfortunately, experiments using cryogenic buffer gases have found that although the molecular motion and rotation are quickly cooled, the molecular vibration relaxes at impractically long timescales. Here, we theoretically explain the recently observed exception to this rule: efficient vibrational cooling of BaCl+ by a laser-cooled Ca buffer gas. We perform intense close-coupling calculations that agree with the experimental result, and use both quantum defect theory and a statistical capture model to provide an intuitive understanding of the system. This result establishes that, in contrast to the commonly held opinion, there exists a large class of systems that exhibit efficient vibrational cooling and therefore supports a new route to realize the long-sought opportunities offered by molecular structure.
Description
Citation
Citation to related work
Springer Science and Business Media LLC
Has part
Nature Communications
ADA compliance
For Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu