Genre
Journal ArticleDate
2016-06-22Author
Martinez, LPUmemiya, S
Wengryniuk, SE
Baran, PS
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http://hdl.handle.net/20.500.12613/4191
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10.1021/jacs.6b04816Abstract
© 2016 American Chemical Society. The structurally intriguing terpenes pallambins C and D have been assembled in only 11 steps from a cheap commodity chemical: furfuryl alcohol. This synthesis, which features a redox-economic approach free of protecting-group manipulations, assembles all four-ring systems via a sequential cyclization strategy. Of these four-ring constructing operations, two are classical (Robinson annulation and Mukaiyama aldol) and two are newly devised. During the course of this work a method for the difunctionalization of enol ethers was developed, and the scope of this transformation was explored.Citation to related work
American Chemical Society (ACS)Has part
Journal of the American Chemical SocietyADA compliance
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http://dx.doi.org/10.34944/dspace/4173