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dc.contributor.advisorSieburth, Scott McNeill
dc.creatorChen, Peiling
dc.date.accessioned2020-10-21T14:27:02Z
dc.date.available2020-10-21T14:27:02Z
dc.date.issued2010
dc.identifier.other864884786
dc.identifier.urihttp://hdl.handle.net/20.500.12613/950
dc.description.abstract2-Pyridones such as iii undergo efficient [4+4] photocycloaddition reactions, yielding strained tricyclic cyclooctadiene structures iv and v, with functionality at every carbon. As part of a program to develop the chemistry of these complex adducts, three studies have been conducted. Halogenation of trans iv give rearranged i. Cope rearrangement of cis v gives vi which can undergo retro-Mannich reaction to yield unsymmtrically coupled piperidines vii. Pyridones can also undergo photo-[4+4] reactions with furans. Cycloaddition of viii yields ix. Transannular closure of ix produces triquinane x, a model system for total synthesis of crinipellin A xi.
dc.format.extent520 pages
dc.language.isoeng
dc.publisherTemple University. Libraries
dc.relation.ispartofTheses and Dissertations
dc.rightsIN COPYRIGHT- This Rights Statement can be used for an Item that is in copyright. Using this statement implies that the organization making this Item available has determined that the Item is in copyright and either is the rights-holder, has obtained permission from the rights-holder(s) to make their Work(s) available, or makes the Item available under an exception or limitation to copyright (including Fair Use) that entitles it to make the Item available.
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subjectChemistry, Organic
dc.titleTHREE STUDIES OF 2-PYRIDONE PHOTOADDUCT REACTIVITY
dc.typeText
dc.type.genreThesis/Dissertation
dc.contributor.committeememberDavis, Franklin A.
dc.contributor.committeememberKrow, Grant
dc.description.departmentChemistry
dc.relation.doihttp://dx.doi.org/10.34944/dspace/932
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.description.degreePh.D.
refterms.dateFOA2020-10-21T14:27:02Z


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