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dc.creatorBecica, Joseph
dc.creatorDobereiner, Graham
dc.date.accessioned2020-04-22T14:17:24Z
dc.date.available2020-04-22T14:17:24Z
dc.date.issued2019-01-22
dc.identifier.citationBecica, Joseph & Dobereiner, Graham E. (2019). The roles of Lewis acidic additives in organotransition metal catalysis. Org. Biomol. Chem., 2019, 17: 2055-2069. https://doi.org/10.1039/c8ob02856g.
dc.identifier.issn1477-0520
dc.identifier.doihttp://dx.doi.org/10.34944/dspace/53
dc.identifier.urihttp://hdl.handle.net/20.500.12613/66
dc.description.abstractWe describe recent examples of prominent reactions in organic synthesis that involve transition metal and Lewis acid cocatalysts. Introducing Lewis acid additives to transition metal catalysis can enable new reactivity or improve activity and selectivity of an existing process. Several studies are highlighted to illustrate the possible roles of Lewis acids in catalytic mechanisms. The uses of Lewis acid additives in bond-breaking catalysis (C–C activation, C–H activation, and hydrogenolysis reactions) and bond-forming catalysis (Au-catalysed alkyne functionalisation, Pd-catalysed C–C and C–N bond formation) are reviewed.
dc.format.extent15 pages
dc.languageEnglish
dc.language.isoeng
dc.relation.ispartofFaculty/ Researcher Works
dc.relation.haspartOrganic & Biomolecular Chemistry, Vol. 17, Iss. 8
dc.relation.isreferencedbyThe Royal Society of Chemistry
dc.rightsAttribution-NonCommercial CC BY-NC
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.titleThe roles of Lewis acidic additives in organotransition metal catalysis
dc.typeText
dc.type.genreArticle (Other)
dc.description.departmentChemistry
dc.relation.doihttps://doi.org/10.1039/c8ob02856g
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.description.schoolcollegeTemple University. College of Science and Technology
dc.description.sponsorNational Science Foundation (U.S.)
dc.creator.orcid0000-0001-6885-2021
dc.temple.creatorBecica, Joseph
dc.temple.creatorDobereiner, Graham E.
refterms.dateFOA2020-04-22T14:17:24Z


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