Permanent link to this recordhttp://hdl.handle.net/20.500.12613/6084
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AbstractMetal-free homoallylic oxygen-directed intramolecular hydroboration is reported. Regioselectivities from 20:1 to 82:1 favoring the 1,3-dioxy-substituted products have been achieved using Me2S·BH3/TfOH followed by standard oxidative workup. Branching at the C5 position improves regioselectivity. Copyright © 2008 American Chemical Society.
Citation to related workAmerican Chemical Society (ACS)
Has partJournal of the American Chemical Society
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