Show simple item record

dc.creatorPuri, P
dc.creatorSchowalter, SJ
dc.creatorKotochigova, S
dc.creatorPetrov, A
dc.creatorHudson, ER
dc.date.accessioned2021-02-03T18:56:14Z
dc.date.available2021-02-03T18:56:14Z
dc.date.issued2014-07-07
dc.identifier.issn0021-9606
dc.identifier.issn1089-7690
dc.identifier.doihttp://dx.doi.org/10.34944/dspace/5857
dc.identifier.otherAM1QG (isidoc)
dc.identifier.other25005291 (pubmed)
dc.identifier.urihttp://hdl.handle.net/20.500.12613/5875
dc.description.abstractThe photodissociation cross-section of SrCl+ is measured in the spectral range of 36000-46000 cm-1 using a modular time-of-flight mass spectrometer (TOF-MS). By irradiating a sample of trapped SrCl+ molecular ions with a pulsed dye laser, X1Σ+ state molecular ions are electronically excited to the repulsive wall of the A 1Π state, resulting in dissociation. Using the TOF-MS, the product fragments are detected and the photodissociation cross-section is determined for a broad range of photon energies. Detailed ab initio calculations of the SrCl+ molecular potentials and spectroscopic constants are also performed and are found to be in good agreement with experiment. The spectroscopic constants for SrCl+ are also compared to those of another alkaline earth halogen, BaCl+, in order to highlight structural differences between the two molecular ions. This work represents the first spectroscopy and ab initio calculations of SrCl+. © 2014 AIP Publishing LLC.
dc.format.extent014309-014309
dc.language.isoen
dc.relation.haspartJournal of Chemical Physics
dc.relation.isreferencedbyAIP Publishing
dc.subjectphysics.chem-ph
dc.subjectphysics.chem-ph
dc.subjectphysics.atom-ph
dc.titleAction spectroscopy of SrCl<sup>+</sup> using an integrated ion trap time-of-flight mass spectrometer
dc.typeArticle
dc.type.genreJournal Article
dc.relation.doi10.1063/1.4885363
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.date.updated2021-02-03T18:56:12Z
refterms.dateFOA2021-02-03T18:56:15Z


Files in this item

Thumbnail
Name:
1404.4609v1.pdf
Size:
1.565Mb
Format:
PDF

This item appears in the following Collection(s)

Show simple item record