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dc.creatorHerrera, F
dc.creatorSpano, FC
dc.date.accessioned2021-02-03T16:13:09Z
dc.date.available2021-02-03T16:13:09Z
dc.date.issued2016-06-08
dc.identifier.issn0031-9007
dc.identifier.issn1079-7114
dc.identifier.doihttp://dx.doi.org/10.34944/dspace/5696
dc.identifier.otherDN8OQ (isidoc)
dc.identifier.other27341263 (pubmed)
dc.identifier.urihttp://hdl.handle.net/20.500.12613/5714
dc.description.abstract© 2016 American Physical Society. The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an electronic transition can effectively decouple collective electronic and nuclear degrees of freedom in a disordered molecular ensemble, even for molecules with high-frequency quantum vibrational modes having strong electron-vibration interactions. This type of polaron decoupling can be used to control chemical reactions. We show that the rate of electron transfer reactions in a cavity can be orders of magnitude larger than in free space for a wide class of organic molecular species.
dc.format.extent238301-
dc.language.isoen
dc.relation.haspartPhysical Review Letters
dc.relation.isreferencedbyAmerican Physical Society (APS)
dc.subjectquant-ph
dc.subjectquant-ph
dc.subjectphysics.chem-ph
dc.titleCavity-Controlled Chemistry in Molecular Ensembles
dc.typeArticle
dc.type.genreJournal Article
dc.relation.doi10.1103/PhysRevLett.116.238301
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.date.updated2021-02-03T16:13:06Z
refterms.dateFOA2021-02-03T16:13:09Z


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