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dc.creatorMartinez, LP
dc.creatorUmemiya, S
dc.creatorWengryniuk, SE
dc.creatorBaran, PS
dc.date.accessioned2020-12-08T21:38:43Z
dc.date.available2020-12-08T21:38:43Z
dc.date.issued2016-06-22
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.doihttp://dx.doi.org/10.34944/dspace/4173
dc.identifier.other27284962 (pubmed)
dc.identifier.urihttp://hdl.handle.net/20.500.12613/4191
dc.description.abstract© 2016 American Chemical Society. The structurally intriguing terpenes pallambins C and D have been assembled in only 11 steps from a cheap commodity chemical: furfuryl alcohol. This synthesis, which features a redox-economic approach free of protecting-group manipulations, assembles all four-ring systems via a sequential cyclization strategy. Of these four-ring constructing operations, two are classical (Robinson annulation and Mukaiyama aldol) and two are newly devised. During the course of this work a method for the difunctionalization of enol ethers was developed, and the scope of this transformation was explored.
dc.format.extent7536-7539
dc.language.isoen
dc.relation.haspartJournal of the American Chemical Society
dc.relation.isreferencedbyAmerican Chemical Society (ACS)
dc.subjectChemistry Techniques, Synthetic
dc.subjectDiterpenes
dc.subjectFurans
dc.subjectMolecular Structure
dc.subjectOxidation-Reduction
dc.title11-Step Total Synthesis of Pallambins C and D
dc.typeArticle
dc.type.genreJournal Article
dc.relation.doi10.1021/jacs.6b04816
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.date.updated2020-12-08T21:38:39Z
refterms.dateFOA2020-12-08T21:38:43Z


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