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dc.contributor.advisorDavatzes, Alexandra K.
dc.creatorHibbard, Shannon Maria
dc.date.accessioned2020-10-26T19:19:22Z
dc.date.available2020-10-26T19:19:22Z
dc.date.issued2017
dc.identifier.urihttp://hdl.handle.net/20.500.12613/1434
dc.description.abstractImpact spherules are sand-sized spherical particles that have been interpreted to have formed by the cooling, crystallization, and quenching of melt droplets condensed from vapor plumes that are created during large meteor impacts. Spherules may be deposited globally as unique marker beds, such as at the K-Pg boundary. A minimum of 11 spherule beds have been identified in the Archean and Paleoproterozoic, and provide a record of impact events that predate any known craters. This study of 3.24 Ga impact spherules from the S3 spherule layer in the Barberton Greenstone Belt (BGB) in the Kaapvaal Craton of South Africa focuses on the heterogeneity of textures and geochemistry produced during the cooling and crystallization of spherules within a vapor plume. Type 4b spherules are layered phyllosilicate spherules with discrete differences in texture and composition between the inner and outer layer, even after alteration. Compositionally layered phyllosilicate spherules were analyzed using Energy Dispersive X-ray Spectroscopy (EDS) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) to measure major, trace, and rare earth element (REE) concentrations. Backscatter Electron (BSE) images and elemental X-ray maps indicate a range of compositional differences between the inner and outer layers of type 4b spherules. The majority of REE plots have nearly flat patterns, with little to no light to heavy REE fractionation; however, the outer layers consistently have higher concentrations, averaging about 10x chondritic, whereas the interiors are at or below chondritic levels with a mid-REE enrichment. The trace and REE patterns of the type 4b spherules are consistent with a more mafic inner layer and a more intermediate outer layer. Mechanisms to produce this layered texture may include: (1) accretion of less mafic material from the plume onto existing melt droplets as the plume continues to fractionate, (2) collision of melt droplets of different viscosities, (3) by differentiation within the melt droplet prior to crystallization, or (4) by diagenetic effects. Based on textures, such as distinct boundaries between layers, and compositional patterns, such as an enrichment of Ti and REE in the outer layer, the data best fits the particle collision formation mechanism hypothesis, which has important implications for impact plume studies, such as plume density, turbulence, temperature, and opacity.
dc.format.extent204 pages
dc.language.isoeng
dc.publisherTemple University. Libraries
dc.relation.ispartofTheses and Dissertations
dc.rightsIN COPYRIGHT- This Rights Statement can be used for an Item that is in copyright. Using this statement implies that the organization making this Item available has determined that the Item is in copyright and either is the rights-holder, has obtained permission from the rights-holder(s) to make their Work(s) available, or makes the Item available under an exception or limitation to copyright (including Fair Use) that entitles it to make the Item available.
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subjectPlanetology
dc.subjectGeochemistry
dc.subjectSedimentary Geology
dc.subjectArchean
dc.subjectBarberton
dc.subjectGeochemistry
dc.subjectImpacts
dc.subjectPetrography
dc.subjectSpherules
dc.titleTrace Element Geochemistry of Compositionally Layered Impact Spherules
dc.typeText
dc.type.genreThesis/Dissertation
dc.contributor.committeememberChemtob, Steven M.
dc.contributor.committeememberGrandstaff, David E.
dc.description.departmentGeology
dc.relation.doihttp://dx.doi.org/10.34944/dspace/1416
dc.ada.noteFor Americans with Disabilities Act (ADA) accommodation, including help with reading this content, please contact scholarshare@temple.edu
dc.description.degreeM.S.
refterms.dateFOA2020-10-26T19:19:22Z


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