• CO-PRODUCTION OF GEOGRAPHIC KNOWLEDGE FOR THE SOCIO-ECOLOGICAL RESTORATION AND DEMOCRATIC GOVERNANCE OF URBAN-RURAL RIPARIAN ZONES IN MEDELLIN, COLOMBIA.

      Hayes-Conroy, Allison, 1981-; Gutierrez-Velez, Victor H.; Pearsall, Hamil; Burns, Ryan (Temple University. Libraries, 2020)
      Progressive scholars have found in community-engaged research and participatory methodologies a synergistic approach for pursuing transformative co-production of knowledge to understand the complexity of critical social and environmental issues. According to Jasanooff (2004), the co-production of knowledge is "the simultaneous process through which modern societies form their epistemic and normative understandings of the world." This dissertation project has sought the co-production of geographic knowledge in socio-environmental research on stream restoration, co-produced between academics and community activists in Medellin, Colombia. Specifically, the intent of the research has been to examine the latent power of affect and feeling to promote the ecological care of streams and their surrounding basins, and to understand the possibilities of mapping the desires that local ecological actors have for stream restoration. Papers one and two also made key contributions to understanding how environmental and social actors surrounding La Honda stream are or could contribute to a scenario of the stream basin’s ecological care. In paper three I detailed my work on the ElAtlas initiative. There I documented the rich historical process we went through to build ElAtlas. I described how the initiative involved the convergence of different participatory approaches in GIS, such as Public Participatory GIS (PPGIS), and Volunteered Geographic Information (VGI), and richly detailed the three different stages of the initiative.
    • COMBINED OZONE AND ULTRASOUND PROCESS FOR THE DESTRUCTION OF 1,4-DIOXANE IN CONTINUOUS FLOW REACTOR

      Suri, Rominder P. S.; Zhang, Huichun (Judy); McKenzie, Erica R.; Hutapea, Parsaoran (Temple University. Libraries, 2016)
      Clean water is essential to life. Growth in world population, changing diets, and a warming climate are driving an increase in the demand for water. Better management of water resources will help prevent scarcity, but in order to fully meet the future demand for safe, clean drinking water, new water treatment technologies are needed. This dissertation investigates a technology which is not well understood; the combination of ozone and ultrasound as potentially an efficient technology. Since nearly all previously published studies of combined ozone/ultrasound utilized batch reactors, a continuous flow reactor was constructed for this research. 1,4-Dioxane, henceforth referred to as dioxane, was chosen to evaluate the effectiveness of the combined ozone/ultrasound process. Dioxane is commonly detected in surface and groundwater and is a suspected human carcinogen. A recalcitrant contaminant, it resists direct oxidation by chlorine, oxygen, ozone, and biological treatment. It is miscible in water and doesn't sorb readily to organic matter, so it spreads rapidly in groundwater contamination plumes. It also resists air stripping and filtration, including reverse osmosis. For these reasons, dioxane makes an excellent candidate to measure the effectiveness of advanced oxidation processes, such as combined ozone/ultrasound. The treatment of dioxane by advanced oxidation processes has been studied extensively in the past. However, only one study has been published using combined ozone/ultrasound, and it was done in a batch reactor operating at a high ultrasonic frequency. The reactor built for this study also permitted reactor pressurization effects to be studied in a manner that has not been reported before for the combined ozone/ultrasound process. In this study, the combination of ozone and ultrasound was found to cause synergistic removal of dioxane from drinking water; the removal achieved by the combination significantly exceeded the sum of the removal achieved by ozone and ultrasound separately. In fact, the combination of ozone and ultrasound was found to remove more than double the dioxane that would be removed by doing both treatment processes separately. Ultrasound (20 kHz) was ineffective in removing dioxane alone, achieving less than 20% removal. At 16 mg/L, ozone alone was found to achieve removal of up to 86% after a 16 minute treatment time, but appears sensitive to matrix effects, especially pH. When ultrasound was combined with just 1.2 mg/L of aqueous ozone, over 90% removal occurred after a 16 minute treatment. Removal of dioxane was found to be driven not by ozone itself, but by radicals, suggesting that the decomposition of ozone is responsible for the generation of radical species and subsequent removal of dioxane. Ultrasound was found to increase the decomposition of ozone and appeared to be driving increased mass transfer of ozone into the aqueous phase. Modest reactor pressure appears to aid dioxane removal, but further increases in pressure did not appear to further enhance removal. An empirical model was constructed using a form similar to the Chick & Watson model for disinfection. Given inputs of initial aqueous ozone concentration, initial dioxane concentration, treatment time, and ultrasonic power, the model is able to predict effluent concentrations of dioxane with a relative root mean squared error of less than 5%. Additionally, RCT and mass balance analyses were performed, and both analysis techniques suggested that the removal of dioxane is dependent on the consumption of aqueous ozone. Spiked drinking water is representative of water that has undergone conventional treatment but requires a polishing step, and the combined ozone/ultrasound has shown promise as a polishing technology. Owing to its recalcitrance, prevalence, and mobility, dioxane represents a real and challenging groundwater contaminant, and combined ozone/ultrasound has shown promise as a groundwater treatment option. Additionally, the process is capable of dioxane removal in a pH range of 4-10. This pH independence, coupled with its ability to degrade recalcitrant contaminants, suggests that combined ozone/ultrasound holds promise as an industrial wastewater treatment option, too. The removal achieved by both ozone and combined ozone/ultrasound was an order of magnitude greater than what has been reported in previously published reports. However, a comparison of cost effectiveness relative to other advanced oxidation processes remains an area for future study. Finally, the combined ozone/ultrasound process holds promise as a drinking water treatment option in remote areas, since it requires only electricity. As a promising technology for polishing water for reuse, treating contaminated groundwater, treating industrial wastewater, and potentially improving access to safe drinking water in remote areas, combined ozone/ultrasound could aid in meeting global water demand in the future.
    • MONITORING STORMWATER INFILTRATION IN A VACANT LOT COMPARING TIME-LAPSE ELECTROMAGNETIC INDUCTION AND ELECTRICAL RESISTIVITY TOMOGRAPHY

      Toran, Laura E.; Nyquist, Jonathan; Ravi, Sujith (Temple University. Libraries, 2018)
      Vacant lots in cities and surrounding urban areas can potentially be used for stormwater management because they are pervious. However, the extent to which vacant lots provide pervious cover to increase infiltration and reduce stormflow is poorly understood. The goal of this study was to develop faster methods for monitoring stormwater infiltration to improve characterization of heterogeneous urban systems. Geophysical techniques are capable of mapping and characterizing subsurface materials, but are often limited by time and sensitivity constraints. In this study, the infiltration characteristics of a vacant lot created by the demolition of a house was characterized using a series of modeling, field and lab experiments. Site characterization under background conditions with an EM Profiler was used to map zones of different fill materials. Three zones were identified in the study site: grass area, driveway area, and a former house area. Transient soil moisture conditions were monitored during irrigation tests using two geophysical methods (electrical resistivity tomography [ERT] and electromagnetic induction [EM]) to evaluate method sensitivity and differences between the three zones. ERT proved more sensitive than EM profiling at detecting changes in the three zones. Soil moisture changes in the driveway area were particularly difficult to detect using EM. The EM Profiler showed a reduction rather than increase in conductivity at the start of irrigation and storms, which was attributed to flushing of high conductivity pore fluids by dilute irrigation or rain water. This explanation was supported using Archie’s Law to model the response of apparent conductivity under highly conductive pore fluid conditions. The EM Profiler was also used under natural precipitation conditions to quickly monitor areas too large for the ERT to reasonably survey. The results suggested that EM instrument drift needs to be corrected to make the method more sensitive. It was difficult to detect differences in hydrologic characterization between areas of the vacant lot using traditional soil point measurements because of the inherent spatial variability. The most useful point measurement was soil moisture loggers. Data from soil moisture loggers was used to parameterize the model; in addition, the soil moisture loggers showed a slow drying period. By combining the EM Profiler method with soil moisture data and applying corrections for drift, some improvement in sensitivity might be achieved. Quantitative characterization of fill material was shown by ERT, which detected more heterogeneous infiltration in the area of the former house than in the grass area.
    • UNDERSTANDING AND MODELING THE SORPTION ON ANION EXCHANGE RESINS USING POLY-PARAMETER LINEAR FREE-ENERGY RELATIONSHIPS AND PHASE CONVERSION

      Zhang, Huichun; Suri, Rominder P. S.; Van Aken, Benoit (Temple University. Libraries, 2013)
      Priority organic and emerging contaminants are a growing concern for drinking water treatment due to their increasing presence in the environment. This study developed a predictive model for the sorption of anionic organic contaminants from drinking water on three anion exchange resins: a strong polystyrenic (IRA-910), weak polystyrenic (IRA-96), and a strong polacrylic (A860). The model quantifies the individual mechanisms of sorption using poly-parameter linear free energy relationships (pp-LFERs) and the feasibility of phase conversion (e.g., an ideal gas phase as the reference state) for ionic species was examined. To develop the model, a training set of isotherms was obtained using aliphatic and aromatic carboxylates, phenols, anilines, nitrobenzene, and ibuprofen. These compounds were chosen as model organic contaminants in the environment. The training set and 1-3 test compounds (3-methyl-2-nitrobenzoate, phenol, and 4-nitroaniline) were accurately predicted using the created model for each resin. An understanding of the effects of resin structure on sorption interactions was also developed that focused on ionic functional groups, resin matrix, and hydrophilicity (i.e. water content). It was shown that greater sorption efficiency was achieved when electrostatic (ion exchange) and nonelectrostatic (adsorption) interactions were present together to create a synergistic addition. However, sorption on ion exchangers was poor if the pH of the system approached levels lower than the sorbate pKa. Additionally, weak base exchanges lose exchange capacity as pH levels approach resin pKa (IRA-96 pKa = 6.0). Additional contributions to the sorption mechanisms were observed by studying various electron donating/withdrawing functional groups on the contaminants. It was concluded that π-π and H-bonding interactions contributed a greater amount to the nonelectrostatic mechanisms than cavity formation forces and nonspecific forces. A comparison between the three resins showed that IRA-96 (weak base polystyrenic) had a greater removal capacity than IRA-910 (strong base polystyrenic), followed far behind by A860 (strong base polyacrylate). This is due to differences between the resins, such as the hydrophilicity, the density of the ion exchange group, and the presence of aromatic rings within the matrix structure. Although the modeling method accurately predicted the phase change from aqueous to sorbent phases, it was shown that the SPARC calculated aqueous-gas ion transfer energies were poor estimations of the transfer energy to the ideal gas phase and further study is necessary to accurately determine this value. This modeling methodology is believed to be applicable to emerging contaminants such as pharmaceuticals in water systems and helps further new water treatment technologies while developing a mechanistic understanding of electrostatic and nonelectrostatic interactions in general. This can be applied to additional separation processes such as chemical purification and chromatographic separation.